Тип публикации: статья из журнала
Год издания: 2013
Идентификатор DOI: 10.1134/S1063776113010111
Ключевые слова: Average numbers, D electrons, External pressures, High pressure, Hubbard, Insulator-metal phase, Spin crossovers, Metal insulator boundaries, Semiconductor insulator boundaries
Аннотация: Possible variants of the Mott-Hubbard phase transitions at high pressure in systems with spin crossovers are considered. Owing to the universal character of the dependence of the effective Hubbard parameter U (eff)(d (n) ) on the average number of d electrons, which is determined by the presence of spin crossovers, cascades of insuПоказать полностьюlator-metal-insulator phase transitions in systems with d (3), d (6), and d (8) configurations become possible. Moreover, the systems with d (6) configuration can exhibit transitions from a metal in the absence of external pressure to an insulator at high pressure.
Журнал: JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS
Выпуск журнала: Vol. 116, Is. 1
Номера страниц: 123-127
ISSN журнала: 10637761
Место издания: NEW YORK
Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER