Тип публикации: статья из журнала
Год издания: 1998
Аннотация: The equilibrium of thiourea protonation in aqueous solutions of hydrochloric and perchloric acids is studied spectrophotometrically. The value of the logarithm of the protonation constant at the zero-value ionic strength is found to be -1.58. The protonation constants for thiourea in aqueous solutions of HCl-MCl (M = Li, Na, K, Cs)Показать полностьюand HClO4-NaClO4 are determined. It is shown that the equilibria of protonation of weak bases should be considered in terms of the theory of specific interaction.
Журнал: Russian Journal of Physical Chemistry A
Выпуск журнала: Vol. 72, Is. 3
Номера страниц: 383-386