Raman and infrared characterization of gadolinium-doped manganese sulfide

Описание

Тип публикации: статья из журнала

Год издания: 2017

Идентификатор DOI: 10.1080/00387010.2017.1287092

Ключевые слова: Infrared, lattice dynamics, manganese sulfide, Raman

Аннотация: Gadolinium manganese sulfide solid solutions are investigated by infrared and Raman spectroscopy. Longitudinal optical-transverse optical splitting of the manganese-sulfur bond vibration is observed in the vibrational spectra. The Raman spectra contain modes that are prohibited in the crystal structure of the alpha phase of manganeПоказать полностьюse sulfide, which are associated with activation of the phonons from both the Brillouin zone center and its X and L points. The concentration dependence of transverse optical and longitudinal optical modes' frequencies is calculated within the frame of the modified random-element-isodisplacement model, being in good agreement with the experimental results. Both theory and experiment show that the solid solution under study exhibits a "one-mode" behavior.

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Издание

Журнал: SPECTROSCOPY LETTERS

Выпуск журнала: Vol. 50, Is. 1

Номера страниц: 55-58

ISSN журнала: 00387010

Место издания: PHILADELPHIA

Издатель: TAYLOR & FRANCIS INC

Авторы

  • Gerasimova Y.V. (Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Mol Spect, Krasnoyarsk, Russia; Siberian Fed Univ, Dept Expt Phys & Innovat Technol, Krasnoyarsk, Russia)
  • Oreshonkov A.S. (Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Mol Spect, Krasnoyarsk, Russia; Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk, Russia)
  • Romanova O.B. (Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Resonance Properties Magnet Ordered Media, Krasnoyarsk, Russia)
  • Ivanenko A.A. (Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Mol Spect, Krasnoyarsk, Russia)
  • Krylov A.S. (Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Lab Mol Spect, Krasnoyarsk, Russia)

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