Pb6O5(NO3)2: A Nonlinear Optical Oxynitrate Structurally Based on Lead Oxide Framework

Описание

Тип публикации: статья из журнала

Год издания: 2020

Идентификатор DOI: 10.1021/acs.inorgchem.0c00001

Аннотация: A high second harmonic generation response is demonstrated by a Pb6O5(NO3)2 lead oxynitrate whose identity was verified upon reinvestigation of the PbO-Pb(NO3)2 system. Its crystal structure exhibits a unique cationic [Pb6O5]2+ framework hosting orientationally ordered NO3 - triangles in the channels. Easy preparation and high therПоказать полностьюmal stability (until ∼500 °C in air) suggest it to be a new promising NLO material. © 2020 American Chemical Society.

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Издание

Журнал: Inorganic Chemistry

ISSN журнала: 00201669

Авторы

  • Charkin D.O. (Department of Chemistry, Moscow State University, Leninskie Gory 1, Moscow, 119991, Russian Federation)
  • Borisov A.S. (Department of Crystallography, St. Petersburg State University, St. Petersburg, 199034, Russian Federation)
  • Plokhikh I.V. (Institute of Inorganic Chemistry, University of Regensburg, Regensburg, 93053, Germany)
  • Stefanovich S.Y. (Department of Chemistry, Moscow State University, Leninskie Gory 1, Moscow, 119991, Russian Federation)
  • Zadoya A.I. (Department of Crystallography, St. Petersburg State University, St. Petersburg, 199034, Russian Federation)
  • Zaloga A.N. (Siberian Federal University, Svobodny Prosp. 79/10, Krasnoyarsk, 660041, Russian Federation)
  • Semenova T.F. (Department of Crystallography, St. Petersburg State University, St. Petersburg, 199034, Russian Federation)
  • Siidra O.I. (Department of Crystallography, St. Petersburg State University, St. Petersburg, 199034, Russian Federation, Kola Science Center, Russian Academy of Sciences, Apatity, Murmansk Region, 184200, Russian Federation)

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