Crystal Structure of Three Ionic Compounds of Levofloxacin

Описание

Тип публикации: статья из журнала

Год издания: 2019

Идентификатор DOI: 10.1134/S0022476619120114

Ключевые слова: double charged levofloxacinium cation, ionic compounds, structure, tetrahalides of d-elements

Аннотация: The structures of three ionic compounds of levofloxacin (LevoH or Ci18H20FN3O4) − LevoH3[CoCl4]-H2O (I), LevoH3[ZnBr4]·H2O (II), LevoH3[CuBr4]-H2O·(III) are determined. The crystals of I-III are monoclinic; in compound III, the particles are packed so that the direction of the screw axis does not coincide with the largest unit cellПоказать полностьюparameter. The asymmetric unit of the unit cell contains two LevoH3 2+ and CoCl4 2− ions and two crystallization water molecules in I; two LevoH3 2+ and MBr4 2− (M = Cu, Zn) ions and two crystallization water molecules in II and III. The absolute structure of the crystals and the configuration of the chiral center of the levofloxacinium cation S are determined. The structures are stabilized by multiple hydrogen bonds, X−Y π and π-π interactions. © 2019, Pleiades Publishing, Ltd.

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Издание

Журнал: Journal of Structural Chemistry

Выпуск журнала: Vol. 60, Is. 12

Номера страниц: 1959-1964

ISSN журнала: 00224766

Издатель: Pleiades Publishing

Персоны

  • Vasiliev A.D. (Siberian Fed Univ, Krasnoyarsk, Russia; Russian Acad Sci, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk Sci Ctr,Siberian Branch, Krasnoyarsk, RussiaArticle)
  • Golovnev N.N. (Siberian Fed Univ, Krasnoyarsk, Russia)

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