Crystal structure and magnetic properties of Mn substituted ludwigite Co3O2BO3

Описание

Тип публикации: статья из журнала

Год издания: 2012

Идентификатор DOI: 10.1016/j.jmmm.2011.07.044

Ключевые слова: Transition metal oxyborate, Distinct crystallographic position, Spin glass magnetic ordering, Distinct crystallographic position, Spin glass magnetic ordering, Transition metal oxyborate, Antiferro-magnetic interactions, Crystallographic position, Isostructural, K points, Magnetic properties of co, Mn ions, Needle shape, Temperature dependencies, X-ray diffraction data, Antiferromagnetism, Cobalt, Cobalt compounds, Glass, Magnetic properties, Manganese, Paramagnetism, Single crystals, Spin glass, X ray diffraction, Crystal structure

Аннотация: The needle shape single crystals Co3-x MnxO2BO3 with ludwigite structure have been prepared. According to the X-ray diffraction data the preferable character of distinct crystallographic positions occupation by Mn ions is established. Magnetization field and temperature dependencies are measured. Paramagnetic Curie temperature valuПоказать полностьюe Theta = -100 K points out the predominance of antiferromagnetic interactions. Spin-glass magnetic ordering takes the onset at T-N=41 K. The crystallographic and magnetic properties of Co3O2BO3:Mn are compared with the same for the isostructural analogs Co3O2BO3 and CoO2BO3:Fe. (C) 2011 Elsevier B.V. All rights reserved.

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Издание

Журнал: JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS

Выпуск журнала: Vol. 324, Is. 6

Номера страниц: 923-927

ISSN журнала: 03048853

Место издания: AMSTERDAM

Издатель: ELSEVIER SCIENCE BV

Авторы

  • Knyazev Y.V. (Siberian Federal University)
  • Ivanova N.B. (Krasnoyarsk State Agrarian University)
  • Velikanov D.A. (L.V. Kirensky Institute of Physics,SB,RAS)
  • Vasiliev A.D. (L.V. Kirensky Institute of Physics,SB,RAS)
  • Ovchinnikov S.G. (Siberian State Aerospace University)
  • Yurkin G.Y. (L.V. Kirensky Institute of Physics,SB,RAS)
  • Kazak N.V. (L.V. Kirensky Institute of Physics,SB,RAS)
  • Platunov M.S. (L.V. Kirensky Institute of Physics,SB,RAS)
  • Bezmaternykh L.N. (L.V. Kirensky Institute of Physics,SB,RAS)

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