Тип публикации: статья из журнала
Год издания: 2018
Идентификатор DOI: 10.1016/j.dyepig.2017.11.009
Ключевые слова: Fluorescence, Molecular structure, Pentacyclic heterocycles, Phenoxazine, Synthesis
Аннотация: Reaction between sterically crowded 3,5-di-(tert-butyl)-o-benzoquinone and aromatic amines occurring at the oxidative conditions and developing to the formation of compounds 8, derivatives of the pentaheterocyclic 12Н-quinoxaline[2,3-b]phenoxazine system 2 was studied. The products obtained at the intermediate stages, including di-Показать полностью(tert-butyl) derivatives of the tricyclic 10H-phenoxazine system: (E)-N-3Н-phenoxazin-3-ylidene-4-methoxyaniline 3, N-(aryl)-3-arylimine-3Н-phenoxazine-2-amine 4, 1-phenyl-10H-phenoxazine 5 and 1-phenyl-3H-phenoxazin-3-one 6 were preparatively isolated and their molecular structures determined by X-ray crystallography. A stable 1-phenyl-6,8-di-(tert-butyl)-10H-phenoxazine radical 7, a primary product of oxidation of 5 was prepared and characterized by the ESR spectroscopy. Compounds 8 exhibit strong red luminescence distinguished by small Stokes shifts, short fluorescent lifetimes and high quantum yields. © 2017 Elsevier Ltd
Журнал: Dyes and Pigments
Выпуск журнала: Vol. 150
Номера страниц: 97-104
ISSN журнала: 01437208
Издатель: Elsevier Ltd