Тип публикации: статья из журнала

Год издания: 2020

Идентификатор DOI: 10.1021/acs.inorgchem.0c01103

Аннотация: Organic-inorganic hybrid metal halides with broad-band emission are currently receiving an increasing interest for their unique light emission properties. Here we report a novel lead-free zero-dimensional (0D) tin halide, (C8H14N2)2SnBr6, in which isolated [SnBr6]4- octahedrons are cocrystallized with organic cations, 1,3-bis(aminoПоказать полностьюmethyl)benzene (C8H14N22+). Upon photoexcitation, the bulk crystals exhibit broad-band green emission peaking at 507 nm with a full width at half-maximum (fwhm) of 82 nm (0.395 eV), a Stokes shift of 157 nm (1.09 eV), and a photoluminescence quantum yield (PLQY) of 36 ± 4%. Combined structural analysis and density functional theory (DFT) calculations indicate that the excited state structural distortion of [SnBr6]4- octahedral units account for the formation of this green emission. The relatively small Stokes shift and narrow fwhm of the emission are hence caused by the reduced distortion of [SnBr6]4- octahedrons and rigid molecular structure. The discovery of lead-free (C8H14N2)2SnBr6 and insight into the mechanism of green emission provide an essential platform toward unveiling the relationship between structure and property for 0D metal halide perovskites. © 2020 American Chemical Society.

Журнал: Inorganic Chemistry

Выпуск журнала: Vol. 59, Is. 14

Номера страниц: 9962-9968

ISSN журнала: 00201669

Издатель: American Chemical Society

• Su B. (State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Technology, South China University of Technology, Guangzhou, 510640, China)
• Song G. (Technical Institute of Physics and Chemistry, University of Chinese Academy of Sciences, Beijing, 100190, China)
• Molokeev M.S. (Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation, Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation)
• Lin Z. (Technical Institute of Physics and Chemistry, University of Chinese Academy of Sciences, Beijing, 100190, China)
• Xia Z. (State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Technology, South China University of Technology, Guangzhou, 510640, China)

• Scopus
• Ядро РИНЦ (eLIBRARY.RU)