Properties of a novel quaterpolymer P(3HB/4HB/3HV/3HHx)

Описание

Тип публикации: статья из журнала

Год издания: 2016

Идентификатор DOI: 10.1016/j.polymer.2016.08.048

Ключевые слова: Polyhydroxyalkanoates, Quaterpolymers, Physicochemical and mechanical properties, Physicochemical and mechanical properties, Polyhydroxyalkanoates, Quaterpolymers, Biocompatibility, Cell culture, Chain length, Chains, Decomposition, 3-Hydroxyhexanoate, Degrees of crystallinity, Elongation at break, Physico-chemical and mechanical properties, Polyhydroxyalkanoates, Quaterpolymers, Short chain lengths, Thermal decomposition temperature, Film preparation

Аннотация: Cupriavidus eutrophus B10646 was used to synthesize a series of polyhydroxyalkanoate (PHA) quaterpolymers composed of the short-chain-length 3-hydroxybutyrate (3HB), 4-hydroxybutyrate (4HB), and 3-hydroxyvalerate (3HV) and the medium-chain-length 3-hydroxyhexanoate (3HHx). The molar fraction of 3HB in the quaterpolymers varied betwПоказать полностьюeen 63.5 and 93.1 mol.%, 3HV - between 1.1 and 24.6 mol.%, 4HB - between 2.4 and 15.6 mol.%, and 3HHx - between 0.4 and 4.8 mol.%. The properties of PHA quaterpolymers were significantly different from those of the P(3HB) homopolymer: they had much lower degrees of crystallinity (up to 30-45%), and lower melting points and thermal decomposition temperatures, with the interval between these temperatures remaining practically unchanged. Films prepared from PHA quaterpolymers were rougher and more porous than P(3HB) films; they showed higher values of elongation at break (up to 6-113%), i.e. were more elastic. Films prepared from PHA quaterpolymers were biocompatible and had no toxic effect on mouse fibroblast NIH 3T3 cells. (C) 2016 Elsevier Ltd. All rights reserved.

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Издание

Журнал: POLYMER

Выпуск журнала: Vol. 101

Номера страниц: 67-74

ISSN журнала: 00323861

Место издания: OXFORD

Издатель: ELSEVIER SCI LTD

Авторы

  • Volova T.G. (Institute of Biophysics of Siberian Branch of Russian Academy of Sciences; Siberian Federal University)
  • Vinogradova O.N. (Siberian Federal University)
  • Zhila N.O. (Institute of Biophysics of Siberian Branch of Russian Academy of Sciences; Siberian Federal University)
  • Kiselev E.G. (Institute of Biophysics of Siberian Branch of Russian Academy of Sciences; Siberian Federal University, 79 Svobodnyi Avenue)
  • Shishatskaya E.I. (Institute of Biophysics of Siberian Branch of Russian Academy of Sciences; Siberian Federal University)
  • Sukovatiy A.G. (Institute of Biophysics of Siberian Branch of Russian Academy of Sciences)
  • Peterson I.V. (Institute of Chemistry and Chemical Technology of Siberian Branch of Russian Academy of Sciences)
  • Vasiliev A.D. (L.V. Kirensky Institute of Physics of Siberian Branch of Russian Academy of Sciences)

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