Rapid Synthesis of Red-Emitting Sr2Sc0.5Ga1.5O5:Eu2+ Phosphors and the Tunable Photoluminescence Via Sr/Ba Substitution : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2021

Идентификатор DOI: 10.1002/adom.202100131

Ключевые слова: Eu <sup>2+</sup>-doped phosphors, light-emitting diodes, photoluminescence, Red emission

Аннотация: Discovering new Eu2+-doped red-emitting phosphors in oxide-based materials is a challenge for white light-emitting diode (WLED) applications. Herein, a highly efficient high-frequency induction heating method is employed to rapidly prepare the red-emitting Sr2Sc0.5Ga1.5O5:Eu2+ phosphors peaking at 614 nm and exhibiting a high photoluminescence quantum yield of 78.4% under the excitation of 440 nm. The structural and spectral analyses suggest that Eu2+ ions tend to enter the [Sc1/Ga1O6] and [Ga2O6] polyhedrons with small coordination numbers, leading to the broadband red emission originated from large crystal field splitting of Eu2+ 5d level. The chemical substitution of Ba in the Sr site enhances the thermal stability and helps to the photoluminescence tuning from 614 to 728 nm in SrBaSc0.5Ga1.5O5:Eu2+. The WLED device fabricated by blending the red Sr1.7Ba0.3Sc0.5Ga1.5O5:Eu2+ and yellow Y3(Al, Ga)5O12:Ce3+ phosphors shows a high color-rendering index (Ra = 91.1), and low color-correlated temperature (CCT = 4750 K). This study aims to provide a new synthesis method and design principle for guiding the development of Eu2+-doped oxide-based red phosphors with low preparation cost; moreover, the photoluminescence tuning strategy via cation substitutions is essential to achieve tunable emission, even the near-infrared luminescence.

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Издание

Журнал: Advanced Optical Materials

ISSN журнала: 21951071

Персоны

  • Yang Z. (State Key Laboratory of Luminescent Materials and Devices,Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques,Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices,School of Materials Science and Engineering,South China University of Technology)
  • Zhou Y. (State Key Laboratory of Luminescent Materials and Devices,Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques,Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices,School of Materials Science and Engineering,South China University of Technology)
  • Qiao J. (State Key Laboratory of Luminescent Materials and Devices,Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques,Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices,School of Materials Science and Engineering,South China University of Technology)
  • Xia Z. (School of Physics and Optoelectronics,South China University of Technology)
  • Molokeev M.S. (Research and Development Department,Kemerovo State University)

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