Synthesis, luminescent properties and theoretical calculations of novel orange-red-emitting Ca2Y8(SiO4)(6)O-2:Sm3+ phosphors for white light emitting diodes


Тип публикации: статья из журнала

Год издания: 2018

Идентификатор DOI: 10.1016/j.dyepig.2017.10.047

Ключевые слова: Ca2Y8(SiO4)6O2, phosphor, photoluminescence, solid state reaction, Ca2Y8(SiO4)(6)O-2, Photoluminescence, Phosphor, Solid state reaction

Аннотация: The novel orange-red-emitting Ca2Y8(SiO4)6O2:Sm3+ phosphors (CYSO:Sm3+) were synthesized via conventional a solid state reaction. The crystal structure and atomic coordinates of CYSO:Sm3+ was characterized by Rietveld refinement. Luminesce properties of as-synthesized CYSO:Sm3+ phosphors are carried out by PL/PLE, decay life time, Показать полностьюthermal quenching as well as reflectance spectrometer and LED fabrications. The results indicates that composition-optimized CYSO:1%Sm3+ exhibits orange-red emission peaks located on 564, 601, 608 and 648 nm attributed to the transitions of 4G5/2 → 6H5/2, 4G5/2 → 6H7/2, 4G5/2 → 6H7/2 and 4G5/2 → 6H9/2, respectively. The decay lifetime of CYSO:Sm3+ phosphors was in the range of 0.37–1.10 ms. The temperature-dependent photoluminescence is decreased to 80% from room temperature to 150 °C, which is superior to that of commercial red phsophpr-Y2O3:Eu3+. The results of LED fabrication by combing 405 chips and blue/green phosphors are demonstrated in this study. Finally, from viewpoint of theoretical calculations, band structure and density of state for CYSO and CYSO:Sm3+ are studied by first principles calculations. All the results indicate that CYSO:Sm3+ phosphors could be a potential material for white light-emitting diodes.

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Журнал: Dyes and Pigments

Выпуск журнала: Т.150, №

Номера страниц: 121-129

ISSN журнала: 01437208

Издатель: Elsevier Science Publishing Company, Inc.


  • Chen Chun-Ting (Chung Yuan Christian Univ, Dept Chem Engn, Chungli, Taiwan; Natl Chung Shan Inst Sci & Technol, Taoyuan, Taiwan)
  • Lin Tzu-Jen (Chung Yuan Christian Univ, Dept Chem Engn, Chungli, Taiwan)
  • Molokeev Maxim S. (RAS, Kirensky Inst Phys, Lab Crystal Phys, Fed Res Ctr KSC,SB, Krasnoyarsk 660036, Russia; Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia; Siberian Fed Univ, Krasnoyarsk 660079, Russia)
  • Liu Wei-Ren (Chung Yuan Christian Univ, Dept Chem Engn, Chungli, Taiwan)

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