Polarization and mass transfer during the electrolysis of molten salts with liquid metallic electrodes

Описание

Тип публикации: статья из журнала

Год издания: 2014

Идентификатор DOI: 10.1134/S0036029514080072

Ключевые слова: Chlorine compounds, Electrodes, Electrolysis, Ionization of liquids, Liquids, Mass transfer, Polarization, Criterion equations, Dissipative structure, Electrochemically active particle, Electrode/electrolyte interfaces, Mass transfer rate, Metallic electrodes, Molten chlorides, Physicochemical property, Electric discharges

Аннотация: Calculations are used to show that the fraction of the overvoltage of the stage of discharge-ionization can be significant in the total overvoltage during the polarization of liquid metallic electrodes in molten chlorides depleted of electrochemically active particles (depending on the type of the dissipative structures that appearПоказать полностьюnear the electrode/electrolyte interface). This finding is taken into account to obtain criterion equations to describe the mass-transfer rate as a function of the physicochemical properties of the electrolyte and the metal electrode. © 2014, Pleiades Publishing, Ltd.

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Издание

Журнал: Russian Metallurgy (Metally)

Выпуск журнала: Vol. 2014, Is. 8

Номера страниц: 599-605

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