Перевод названия: Взаимодействие PdCl2-4 с L-цистином в солянокислых растворах
Тип публикации: статья из журнала
Год издания: 2010
Идентификатор DOI: 10.1134/S0036023610020245
Ключевые слова: Chloride ion concentration, Conditional stability, Hydrochloric acid solution, L-cystine, Monodentate coordination, Sulfur atoms, Acids, Complexation, Coordination reactions, Equilibrium constants, Hydrochloric acid, Palladium, Palladium compounds, Sulfur, Chlorine compounds
Аннотация: The effect of acidity and equilibrium chloride ion concentration on the interaction of with cystine (H2CySS) in hydrochloric acid solutions was studied. Pd(H4CySS) complex was found to form at [Cl-] = 1.0, 0.5, or 0.25 mol/L in the [H+] range from 0.10 to 1.00 mol/L; the relevant equilibrium constant was determined. Monodentate cooПоказать полностьюrdination of cystine to palladium(II) through the sulfur atom was proposed on the basis of analysis of conditional stability constants as functions of [Cl-] and [H+].
Журнал: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Выпуск журнала: Vol. 55, Is. 2
Номера страниц: 291-293
ISSN журнала: 00360236
Место издания: NEW YORK
Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER