Structural, thermal and optical properties of elpasolite-like (NH4)2KZrF7

Описание

Тип публикации: статья из журнала

Год издания: 2019

Идентификатор DOI: 10.1016/j.jssc.2019.06.013

Ключевые слова: Entropy, Heat capacity, Optical properties, Phase transition, Structure

Аннотация: New fluoride compound (NH4)2KZrF7 with the elpasolite structure (sp. gr. Fm-3m) was synthesized by partial cationic substitution in (NH4)3ZrF7 cryolite. Due to small difference in ionic radii of K+ and NH4 +, non-equivalent crystallographic positions 8c a New fluoride compound (NH4)2KZrF7 with the elpasolite structure (sp. gr. Fm-3Показать полностьюm) was synthesized by partial cationic substitution in (NH4)3ZrF7 cryolite. Due to small difference in ionic radii of K+ and NH4 +, non-equivalent crystallographic positions 8c a

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Издание

Журнал: Journal of Solid State Chemistry

Выпуск журнала: Vol. 277

Номера страниц: 376-380

ISSN журнала: 00224596

Издатель: Academic Press Inc.

Персоны

  • Pogoreltsev E.I (Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia; Siberian Fed Univ, Krasnoyarsk 660074, Russia)
  • Mel'nikova S.V (Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia)
  • Molokeev M.S. (Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia; Siberian Fed Univ, Krasnoyarsk 660074, Russia; Far Eastern State Transport Univ, Khabarovsk 680021, Russia)
  • Flerov I.N. (Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia; Siberian Fed Univ, Krasnoyarsk 660074, Russia)
  • Laptash N.M. (RAS, Far Eastern Branch, Inst Chem, Vladivostok 690022, RussiaArticle)